80 Prof. Noked Malachi Department of Chemistry Member of BINA Nano-Energy Center Research Areas Surface directed chemical reaction in vacuum (atomic/molecular layer deposition ALD/MLD) for: 1. Stabilization of batteries electrodes in implanted medical devices 2. Designing arrays of nano-materials with controlled morphology and structure for electrochemical devices 3. Modified metallic anode surfaces for next generation rechargeable batteries Abstract Functional thin film for electrochemical devices In our laboratory we utilize state of the art synthesis techniques for interfacial modification of electrochemically active surfaces by functional thin films. Students in our lab experience synthesis through surface directed chemical reaction in vacuum (atomic/molecular layer deposition ALD/MLD) and in carefully chosen electrolyte solutions (surface directed electrodeposition). The characterization of the synthesized thin films and the fundamental studies of their efficacy as surface modification materials, are conducted using state of the art microscopic and spectroscopic surface analysis facilities available in Bar-Ilan University and currently being constructed in our lab. Atomic/Molecular Layer Deposition (A/ MLD) enables creating uniform, conformal thin films with precise thickness control at the monolayer level. Publications 2022 and 2023 • J Alberto Blázquez, Rudi R Maça, Olatz Leonet, Eneko Azaceta, Ayan Mukherjee, Zhirong Zhao-Karger, Zhenyou Li, Aleksey Kovalevsky, Ana FernándezBarquín, Aroa R Mainar, Piotr Jankowski, Laurin Rademacher, Sunita Dey, Siân E Dutton,Clare P Grey, Janina Drews, Joachim Häcker, Timo Danner, Arnulf Latz, Dane Sotta, M Rosa Palacin, JeanFrédéric Martin, Juan Maria García Lastra, Maximilian Fichtner, Sumana Kundu, Alexander Kraytsberg, Yair EinEli, Malachi Noked, Doron Aurbach. “A practical perspective on the potential of rechargeable Mg batteries”. Energy & Environmental Science, 2023. • Roman R Kapaev,Malachi Noked. ” Anodic instability of carbon in non-alkaline Zn– air batteries”. Chemical Communications, 2023. • Sankalpita Chakrabarty, Yuri Glagovsky, Ananya Maddegalla, Natalia Fridman, Dmitry Bravo-Zhivotovski, Doron Aurbach, Ayan Mukherjee, Malachi Noked. “Correlation between the electrochemical response and main components structure in solutions for rechargeable Mg batteries based on THF and the reaction products of tBuMgCl and AlCl3”. Electrochimica Acta, 2023. • Arka Saha, Ortal Shalev, Sandipan Maiti, Longlong Wang, Sri Harsha Akella, Bruria Schmerling, Sarah Targin, Maria Tkachev, Xiulin Fan, Malachi Noked. “Evolution of ternary LixSnyOz artificial cathodeelectrolyte interphase (ACEI) through ALD: a surface strengthened NCM811 with enhanced electrochemical performances for Li-ion batteries”. Materials Today Energy, 2023. • Sri Harsha Akella, Bagavathi Muniyandi, Daniel Sharon, Ömer Özgür Çapraz, Malachi Noked. “Exploring the impact of lithium halide-based redox mediators in suppressing CO2 evolution in Li–O 2 cells”. Journal of Materials Chemistry A, 2023. • Ananya Maddegalla, Yogendra Kumar, Sankalpita Chakrabarty, Yuri Glagovsky, Bruria Schmerling, Natalia Fridman, Michal Afri, Hagit Aviv, Doron Aurbach, Ayan Mukherjee, Dmitry BravoZhivotovskii, Malachi Noked. “First isolation of solvated MgCl+ species as the sole cations in electrolyte solutions for rechargeable Mg batteries”. Electrochimica Acta, 2023. • Longlong Wang, Ayan Mukherjee, ChangYang Kuo, Sankalpita Chakrabarty, Reut Yemini, Arrelaine A Dameron, Jaime W DuMont, Sri Harsha Akella, Arka Saha, Sarah Taragin, Hagit Aviv, Doron Naveh, Daniel Sharon, Ting-Shan Chan, Hong-Ji Lin, Jyh-Fu Lee, Chien-Te Chen, Boyang Liu, Xiangwen Gao, Suddhasatwa Basu, Zhiwei Hu, Doron Aurbach, Peter G Bruce, Malachi Noked. “High-energy all-solidstate lithium batteries enabled by Co-free LiNiO2 cathodes with robust outside-in structures”. Nature Nanotechnology, 2023. • Akanksha Joshi, Sankalpita Chakraborty, Sri Harsha Akella, Arka Saha, Ayan Mukherjee, Bruria Schmerling, Michal Ejgenberg, Rosy Sharma, Malachi Noked. “High-Entropy Co-Free O3-type Layered Oxyfluoride: A Promising Air-Stable Cathode for Sodium-Ion Batteries”. Advanced Materials, 2023. • Longlong Wang, Guy Rahamim, Kirankumar Vudutta, Nicole Leifer, Ran Elazari, Ilan Behar, Malachi Noked, David Zitoun. “Influence of the Halogen in Argyrodite Electrolytes on the Electrochemical Performance of AllSolid-State Lithium Batteries”. Energy Technology, 2023. • Junbo Zhang, Haikuo Zhang, Suting Weng, Ruhong Li, Di Lu, Tao Deng, Shuoqing Zhang, Ling Lv, Jiacheng Qi, Xuezhang Xiao, Liwu Fan, Shujiang Geng, Fuhui Wang, Lixin Chen, Malachi Noked, Xuefeng Wang, Xiulin Fan. “Multifunctional solvent molecule design enables high-voltage Li-ion batteries”. Nature Communications, 2023. • Mary York, Karl Larson, Kailot C Harris, Eric Carmona, Paul Albertus, Rosy Sharma, Malachi Noked, Ela Strauss, Heftsi Ragones, Diana Golodnitsky. “Solid Batteries Chemistries Beyond Lithium”. Advanced Materials and Device Design, 2023. • Roman R Kapaev, Amit Ohayon, Masato Sonoo, Jonathan Tzadikov, Menny Shalom, Malachi Noked. ”Structureperformance relations for carbons in Zn-air battery cathodes with non-alkaline electrolytes”. Electrochimica Acta, 2023. • Amreen Bano, Malachi Noked, Dan Thomas Major. “Theoretical Insights into High-Entropy Ni-Rich Layered Oxide Cathodes for Low-Strain Li-Ion Batteries”. Chemistry of Materials, 2023. • Shubham Garg, Sarah Taragin, Arka Saha, Olga Brontvein, Kevin Leung, Malachi Noked. “Zn-enriched cathode layer interface via atomic surface reduction of LiNi0. 5Mn1. 5O4: Computational and experimental insights”. Journal of Power Sources, 2023. • Xiaoteng Huang, Ruhong Li, Chuangchao Sun, Haikuo Zhang, Shuoqing Zhang, Ling Lv, Yiqiang Huang, Liwu Fan, Lixin Chen, Malachi Noked, Xiulin Fan. “Solvent-Assisted Hopping Mechanism Enables Ultrafast Charging of Lithium-Ion
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